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Chemical anomalies in polar ice core records are frequently linked to volcanism; however, without the presence of (crypto)tephra particles, links to specific eruptions remain speculative. Correlating tephras yields estimates of eruption timing and potential source volcano, offers refinement of ice core chronologies, and provides insights into volcanic impacts. Here, we report on sparse rhyolitic glass shards detected in the Roosevelt Island Climate Evolution (RICE) ice core (West Antarctica), attributed to the 1.8 ka Taupō eruption (New Zealand)—one of the largest and most energetic Holocene eruptions globally. Six shards of a distinctive geochemical composition, identical within analytical uncertainties to proximal Taupō glass, are accompanied by a single shard indistinguishable from glass of the ~25.5 ka Ōruanui supereruption, also from Taupō volcano. This double fingerprint uniquely identifies the source volcano and helps link the shards to the climactic phase of the Taupō eruption. The englacial Taupō-derived glass shards coincide with a particle spike and conductivity anomaly at 278.84 m core depth, along with trachytic glass from a local Antarctic eruption of Mt. Melbourne. The assessed age of the sampled ice is 230 ± 19 CE (95% confidence), confirming that the published radiocarbon wiggle-match date of 232 ± 10 CE (2 SD) for the Taupō eruption is robust.

 

Abstract Tephra is a unique volcanic product with an unparalleled role in understanding past eruptions, long-term behavior of volcanoes, and the effects of volcanism on climate and the environment. Tephra deposits also provide spatially widespread, high-resolution time-stratigraphic markers across a range of sedimentary settings and thus are used in numerous disciplines (e.g., volcanology, climate science, archaeology). Nonetheless, the study of tephra deposits is challenged by a lack of standardization that inhibits data integration across geographic regions and disciplines. We present comprehensive recommendations for tephra data gathering and reporting that were developed by the tephra science community to guide future investigators and to ensure that sufficient data are gathered for interoperability. Recommendations include standardized field and laboratory data collection, reporting and correlation guidance. These are organized as tabulated lists of key metadata with their definition and purpose. They are system independent and usable for template, tool, and database development. This standardized framework promotes consistent documentation and archiving, fosters interdisciplinary communication, and improves effectiveness of data sharing among diverse communities of researchers. 

The history of atmospheric oxygen ( P O 2 ) and the processes that act to regulate it remain enigmatic because of difficulties in quantitative reconstructions using indirect proxies. Here, we extend the ice-core record of P O 2 using 1.5-million-year-old (Ma) discontinuous ice samples drilled from Allan Hills Blue Ice Area, East Antarctica. No statistically significant difference exists in P O 2 between samples at 1.5 Ma and 810 thousand years (ka), suggesting that the Late-Pleistocene imbalance in O 2 sources and sinks began around the time of the transition from 40- to 100-ka glacial cycles in the Mid-Pleistocene between ~1.2 Ma and 700 ka. The absence of a coeval secular increase in atmospheric CO 2 over the past ~1 Ma requires negative feedback mechanisms such as P co 2 -dependent silicate weathering. Fast processes must also act to suppress the immediate P co 2 increase because of the imbalance in O 2 sinks over sources beginning in the Mid-Pleistocene. 

Tephra is a unique volcanic product that plays an unparalleled role in understanding past eruptions, the long-term behavior of volcanoes, and the effects of volcanism on climate and the environment. Tephra deposits also provide spatially widespread, extremely high-resolution time-stratigraphic markers across a range of sedimentary settings and are used by many disciplines (e.g. volcanology, seismotectonics, climate science, archaeology, ecology, public health and ash impact assessment). In the last two decades, tephra studies have become more interdisciplinary in nature but are challenged by a lack of standardization that often prevents comparison amongst various regions and across disciplines. To address this challenge, the global tephra community has come together through a series of workshops to establish best practice recommendations for tephra studies from sample collection through analysis and data reporting. This new standardized framework will facilitate consistent tephra documentation and parametrization, foster interdisciplinary communication, and improve effectiveness of data sharing among diverse communities of researchers. One specific goal is to use the best practice guidelines to inform digital tool and data repository development. Here we report on 1) a new set of templates for tephra sample documentation, geochemical method documentation and data reporting using recommended best- practice data and metadata fields, 2) a new tephra module added to StraboSpot, an open source geologic mapping and data- recording multi-platform software application, and 3) new implementations and cross-mapping of metadata requirements at SESAR (System for Earth Sample Registration) and EarthChem. Addition of tephra-specific fields to StraboSpot enables users to consistently collect and report essential tephra data in the field which is then automatically saved to an online data repository. A new tephra portal on the EarthChem website will allow users to follow simple workflows to register tephra samples at SESAR and submit microanalytical data to EarthChem. 

Abstract. The S27 ice core, drilled in the Allan Hills Blue IceArea of East Antarctica, is located in southern Victoria Land, ∼80 km away from the present-day northern edge of the RossIce Shelf. Here, we utilize the reconstructed accumulation rate of S27covering the Last Interglacial (LIG) period between 129 ka and 116 ka (where ka indicates thousands of years before present) to infer moisture transport into the region. Theaccumulation rate is based on the ice-age–gas-age differences calculatedfrom the ice chronology, which is constrained by the stable water isotopesof the ice, and an improved gas chronology based on measurements of oxygenisotopes of O2 in the trapped gases. The peak accumulation rate in S27occurred at 128.2 ka, near the peak LIG warming in Antarctica. Even the mostconservative estimate yields an order-of-magnitude increase in theaccumulation rate during the LIG maximum, whereas other Antarctic ice coresare typically characterized by a glacial–interglacial difference of a factorof 2 to 3. While part of the increase in S27 accumulation rates mustoriginate from changes in the large-scale atmospheric circulation,additional mechanisms are needed to explain the large changes. Wehypothesize that the exceptionally high snow accumulation recorded in S27reflects open-ocean conditions in the Ross Sea, created by reduced sea iceextent and increased polynya size and perhaps by a southward retreat of theRoss Ice Shelf relative to its present-day position near the onset of the LIG.The proposed ice shelf retreat would also be compatible with a sea-levelhigh stand around 129 ka significantly sourced from West Antarctica. Thepeak in S27 accumulation rates is transient, suggesting that if the Ross IceShelf had indeed retreated during the early LIG, it would have re-advancedby 125 ka. 

A large volcanic sulfate increase observed in ice core records around 1450 C.E. has been attributed in previous studies to a volcanic eruption from the submarine Kuwae caldera in Vanuatu. Both EPMA–WDS (electron microprobe analysis using a wavelength dispersive spectrometer) and SEM–EDS (scanning electron microscopy analysis using an energy dispersive spectrometer) analyses of five microscopic volcanic ash (cryptotephra) particles extracted from the ice interval associated with a rise in sulfate ca. 1458 C.E. in the South Pole ice core (SPICEcore) indicate that the tephra deposits are chemically distinct from those erupted from the Kuwae caldera. Recognizing that the sulfate peak is not associated with the Kuwae volcano, and likely not a large stratospheric tropical eruption, requires revision of the stratospheric sulfate injection mass that is used for parameterization of paleoclimate models. Future work is needed to confirm that a volcanic eruption from Mt. Reclus is one of the possible sources of the 1458 C.E. sulfate anomaly in Antarctic ice cores.