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The Denali Ice Cores were collected from the summit of Begguya (Mt. Hunter), Denali National Park, Alaska in the summer of 2013. Sampling permits were granted by Denali National Park for the drilling and removal of the ice cores. Here, we use the Cameca SX100 at the University of Maine to examine tephra particles recovered from the ice cores. 

In 2013, two parallel ice cores (commonly referred to as the Denali Ice Cores) were drilled to bedrock on the summit plateau of Begguya, Alaska (62.93 N 151.083 W, 3912 m asl; also known as Mount Hunter). A robust chronology has been developed using a combination of techniques including annual layer counting, sulfate peaks (volcanics), radiocarbon dating and the 1963 atmospheric nuclear weapons testing horizon. Here, we employed tephrochronology practices to isolate and document the presence of the Lena Ash Layer and White River Ash east (WRAe) volcanic eruptions within the ice. We separated tephra from the meltwater and analyzed them using SEM-EDS and EPMA methodologies. The data are not immediately conclusive, and work is still ongoing to understand the findings. 

The Denali Ice Cores were collected from the summit of Begguya (Mt. Hunter), Denali National Park, Alaska in the summer of 2013. Sampling permits were granted by Denali National Park for the drilling and removal of the ice cores. Here, we use the Tescan II at the University of Maine to examine tephra particles recovered from the ice cores. 

A robust chronology has been developed for the Denali Ice Cores, Begguya, Alaska (62.93 N 151.083 W, 3912 m asl (meters above sea level); also known as Mount Hunter) using a combination of techniques including annual‑layer counting, volcanics, radiocarbon dating, and the 1963 atmospheric nuclear‑weapons‑testing horizon. Radiocarbon dating confirms that there is early Holocene ice preserved at the bottom of the Denali Ice Cores. To confirm this, researchers at the University of Maine have produced oxygen‑isotope records. Examining the data from the twin cores, we see replicate isotope profiles in the bottom 8 meters of ice, showing a sharp decrease of δ^18O (oxygen‑18 isotope ratio) of nearly 6 ‰ (permil) near the bottom. To investigate whether this decrease is a climate signal or an artifact of basal‑ice dynamics, we collected trace‑element data across the oxygen‑isotope decrease. Because the basal ice of the Denali Ice Cores contains too high a sediment load to be melted and analyzed with aqueous inductively coupled plasma mass spectrometry (ICP‑MS), we analyzed Na (sodium), Mg (magnesium), Cu (copper), Pb (lead), Al (aluminum), Ca (calcium), Fe (iron), and S (sulfur) in the basal ice (207.35 m to 208.76 m depth) using laser‑ablation inductively coupled plasma mass spectrometry (LA‑ICP‑MS). The data are still being analyzed and compared with data from other methods to determine the cause of the oxygen‑isotope‑signal decrease. Researchers seeking to use this dataset should proceed with caution, as there is some evidence of contamination in the Pb and Cu analyses. 

In the North Pacific, large swings in climate, such as the so-called Little Ice Age, Medieval Climate Anomaly, and the 4.2 ka (thousand years ago) event, have all occurred during the Middle-Late Holocene, providing an opportunity to investigate the regional climate and environmental response to hemisphere-scale changes. Two surface-to-bedrock ice cores (210 meters) recovered from the Begguya plateau (Alaska) have been used to document late Holocene climate variability in the North Pacific, underpinned by an annual layer counted timescale that extends to ~800 AD (190 meters depth). Here we describe new data and approaches being used to investigate Holocene and late Pleistocene conditions on Begguya through stable water isotope analysis performed in the bottom 20 meters of the cores. We have completed a full δ18O-H2O isotope profile for both cores, showing relatively uniform values through the core section thought to contain the 4.2ka event. In contrast, a pronounced but continuous 5‰ (permil) increase in δ18O-H2O occurs approximately 2 meters above the bed. Based on the location and structure of these changes, we tentatively infer that the isotope and chemistry excursions near the bed represent the late Pleistocene-Holocene transition, and the isotope profile in that area possibly shows evidence of a climate reversal akin to the Younger Dryas. 

The use of a laser to cut or drill ice has been proposed and demonstrated multiple times in previous decades as a novel, but never adopted, machining tool in glaciology and paleoclimate studies. However, with the rapid development of high power fiber-laser technology over the past few decades, it is timely to perform further studies using this new tool. An investigation is made herein on the cutting of ice using a Yb-doped fiber laser emitting at a wavelength of 1070 nm, the most extensively developed and highest power fiber laser technology, in pulsed and continuous-wave operation. Visible-light observations of clear tap water ice samples, moving at a constant velocity relative to a pulsed laser beam, demonstrate a linear relationship between the duration of a millisecond-range laser pulse and the depth of the meltwater-free cut formed in response. Thermal imaging of the irradiated face shows that peripheral heating trends linearly for pulse lengths greater than 5 ms. A comparison of pulse trains with a constant time-averaged power suggests that shorter pulses are advantageous in slot-cutting efficiency and in minimizing visible alterations in the surrounding ice. These results demonstrate the viability of powerful fiber-compatible lasers as a tool for ice sample retrieval and processing. 

Hyperspectral imaging (HSI) technology has been increasingly used in Earth and planetary sciences. This imaging technique has been successfully tested on ice cores using VNIR (visible and near-infrared, 380-1000 nm) (Garzonio et al., 2018) and near-infrared (900 - 1700 nm) (McDowell et al, 2023)  line-scan cameras. Results show that  HSI data greatly expand ice core line-scan imaging capabilities, previously used with gray or RGB cameras (see summary in Dey et al., 2023). Combinations of selected HSI bands from the hyperspectral data cube improve feature detection in ice core stratigraphy, and map distribution of volcanic material, dust, air bubbles, fractures, and ice crystals in ice cores. Captured spectral information provides unique fingerprints for specific materials present in ice cores. This method helps to guide ice core sampling because it provides non-destructive, rapid visualization of microstructural properties, layering, bubble contents, increases in dust, or presence of  tephra material. Precise identification of these atmospheric components  is important for understanding past climate drivers reconstructed from ice cores. As part of the COLDEX project (Brook et al., this meeting) we adapted the SPECIM SisuSCS HSI system for ice core imaging. The ice core scanning system is housed inside the ca. -20ºC main NSF ICF freezer, and externally computer-controlled. The operator monitors scanning operations and communicates with personnel inside of the freezer via radio.  The system is equipped with a SPECIM FX10 camera that measures up to 224 bands in the VNIR range. We modified the ice core holder tray and installed a heated enclosure for the camera. The system uses SCHOTT DCR III Fiber Optic light sources with an OSL2BIR bulb from Thorlabs. IR filters are removed to extend the light spectral range beyond the 700 nm limit without heating the ice core surface during rapid (<5 minutes) scanning of an entire meter-long section. Emitted light enters ice at a 45º angle from two top and two bottom light sources. To calibrate absolute reflectance we use three Spectralon panels with 100, 50 and 20% reflectance values with every scan as well as several secondary reflective standards and USAF targets for geometric corrections. We are developing Python-based open source data processing routines and currently comparing HSI data with existing ice core physical and chemical measurements. The goal is to fully integrate the ice core HSI system with ice core processing at the NSF ICF. Dey et al., 2023. Application of Visual Stratigraphy from Line-Scan Images to Constrain Chronology and Melt Features of a Firn Core from Coastal Antarctica. Journal of Glaciology 69(273): 179–90. https://doi.org/10.1017/jog.2022.59.Garzonio et al., 2018. A Novel Hyperspectral System for High Resolution Imaging of Ice Cores: Application to Light-Absorbing Impurities and Ice Structure. Cold Regions Science and Technology 155: 47–57. https://doi.org/10.1016/j.coldregions.2018.07.005.McDowell et al., 2023. A Cold Laboratory Hyperspectral Imaging System to Map Grain Size and Ice Layer Distributions in Firn Cores. Preprint. Ice sheets/Instrumentation. https://doi.org/10.5194/egusphere-2023-2351. 

The history of atmospheric oxygen ( P O 2 ) and the processes that act to regulate it remain enigmatic because of difficulties in quantitative reconstructions using indirect proxies. Here, we extend the ice-core record of P O 2 using 1.5-million-year-old (Ma) discontinuous ice samples drilled from Allan Hills Blue Ice Area, East Antarctica. No statistically significant difference exists in P O 2 between samples at 1.5 Ma and 810 thousand years (ka), suggesting that the Late-Pleistocene imbalance in O 2 sources and sinks began around the time of the transition from 40- to 100-ka glacial cycles in the Mid-Pleistocene between ~1.2 Ma and 700 ka. The absence of a coeval secular increase in atmospheric CO 2 over the past ~1 Ma requires negative feedback mechanisms such as P co 2 -dependent silicate weathering. Fast processes must also act to suppress the immediate P co 2 increase because of the imbalance in O 2 sinks over sources beginning in the Mid-Pleistocene.